Publications

(37) Kraack, J. P.; Sévery, L.; Tilley, S. D.; Hamm, P. Plasmonic Substrates Do Not Promote Vibrational Energy Transfer at Solid-Liquid Interfaces J. Phys. Chem. Lett., 2018, 9, 49–56.
doi: 10.1021/acs.jpclett.7b02855

(36) Moehl, T.; Suh, J.; Sévery, L.; Wick-Joliat, R.;  Tilley, S. D.* Investigation of (Leaky) ALD TiO2 Protection Layers for Water Splitting Photoelectrodes ACS Appl. Mater. Interfaces, 2017, 9, 43614–43622.
doi: 10.1021/acsami.7b12564

(35) Prabhakar, R. R.; Septina, W.; Siol, S.; Moehl, T.; Wick-Joliat, R.; Tilley, S. D.* Photocorrosion-Resistant Sb2Se3 Photocathodes with Earth Abundant MoSx Hydrogen Evolution Catalyst J. Mater. Chem. A, 20175, 23139-23145.
doi: 10.1039/C7TA08993G

(34) Niu, W.; Moehl, T.; Cui, W.; Wick, R.; Zhu, L.; Tilley, S. D.* Extended Light Harvesting with Dual Cu2O-based Photocathodes for High Efficiency Water Splitting Advanced Energy Materials, 2017.

 doi: 10.1002/aenm.201702323

(33) Wang, F.; Septina, W.; Chemseddine, A.; Abdi, F. F.; Friedrich, D.; Bogdanoff, P.; van de Krol, R.; Tilley, S. D.; Berglund, S. P. Gradient self-doped CuBi2O4 with highly improved charge separation efficiency J. Am. Chem. Soc., 2017, 139, 15094–15103.
doi: 10.1021/jacs.7b07847

(32) Septina, W.; Tilley, S. D.* Emerging Earth-Abundant Materials for Scalable Solar Water Splitting  Curr. Opin. Electrochem., 2017, 2, 120-127.
doi: 10.1016/j.coelec.2017.03.010

(31) Pastor, E.; Le Formal, F.; Mayer, M. M.; Tilley, S. D.; Francàs, L.; Mesa, C. A.; Grätzel, M.; Durrant, J. R. Spectroelectrochemical analysis of the mechanism of (photo)electrochemical hydrogen evolution at a catalytic interface Nat. Commun., 2017, 8, 14280.
doi: 10.1038/ncomms14280

(30) Septina. W.; Prabhakar, R. R.; Wick, R.; Moehl, T.; Tilley, S. D.* Stabilized Solar Hydrogen Production with CuO/CdS Heterojunction Thin Film Photocathodes Chem. Mater. 2017, 29, 1735–1743.
doi: 10.1021/acs.chemmater.6b05248

(29) Siol, S.; Hellmann, J. C.; Tilley, S. D.; Grätzel, M.; Morasch, J.; Deuermeier, J.; Jaegermann, W.; Klein, A. Band Alignment Engineering at Cu2O/ZnO Heterointerfaces  ACS Appl. Mater. Interfaces, 20168, 21824–21831.
doi: 10.1021/acsami.6b07325

(28) Azevedo, J.; Tilley, S. D.; Schreier, M.; Stefik, M.; Sousa, C.; Araújo, J. P.; Mendes, A.; Grätzel, M.; Mayer, M. T. Tin Oxide as Stable Protective Layer for Composite Cuprous Oxide Water-Splitting Photocathodes. Nano Energy, 2016, 24, 10–16.
doi: 10.1016/j.nanoen.2016.03.022

(27) Wick, R.; Tilley, S. D.* Photovoltaic and Photoelectrochemical Solar Energy Conversion with Cu2O. J. Phys. Chem. C 2015, 119, 26243–26257.
doi: 10.1021/acs.jpcc.5b08397

(26) Dias, P.; Schreier, M.; Tilley, S. D.; Luo, J.; Azevedo, J.; Andrade, L.; Bi, D.; Hagfeldt, A.; Mendes, A.; Grätzel, M.; et al. Transparent Cuprous Oxide Photocathode Enabling a Stacked Tandem Cell for Unbiased Water Splitting. Adv. Energy Mater. 2015, 5, 1501537
doi: 10.1002/aenm.201501537

(25) Luo, J.; Li, Z.; Nishiwaki, S.; Schreier, M.; Mayer, M. T.; Cendula, P.; Lee, Y. H.; Fu, K. Cao, A.; Nazeeruddin, M. K.; Romanyuk, Y. E.; Buecheler, S.; Tilley, S. D.; Wong, L. H.; Tiwari, A. N.; Grätzel, M. Targeting Ideal Dual-Absorber Tandem Water Splitting Using Perovskite Photovoltaics and CuIn X Ga 1- X Se 2 Photocathodes. Adv. Energy Mater. 20155, 1501520.
doi: 10.1002/aenm.201501520

(24) Morales-Guio, C. G.; Mayer, M. T.; Yella, A.; Tilley, S. D.; Grätzel, M.; Hu, X. An Optically Transparent Iron Nickel Oxide Catalyst for Solar Water Splitting. J. Am. Chem. Soc. 2015, 137, 9927–9936.
doi: 10.1021/jacs.5b05544

(23) Le Formal, F.; Pastor, E.; Tilley, S. D.; Mesa, C. a; Pendlebury, S. R.; Grätzel, M.; Durrant, J. R. Rate Law Analysis of Water Oxidation on a Hematite Surface. J. Am. Chem. Soc. 2015, 137, 6629–6637.
doi: 10.1021/jacs.5b02576

(22) Luo, J.; Tilley, S. D.; Steier, L.; Schreier, M.; Mayer, M. T.; Fan, H. J.; Grätzel, M. Solution Transformation of Cu2O into CuInS2 for Solar Water Splitting. Nano Lett. 2015, 15, 1395–1402.
doi: 10.1021/nl504746b

(21) Schreier, M.; Gao, P.; Mayer, M. T.; Luo, J.; Moehl, T.; Nazeeruddin, M. K.; Tilley, S. D.; Grätzel, M. Efficient and Selective Carbon Dioxide Reduction on Low Cost Protected Cu2O Photocathodes Using a Molecular Catalyst. Energy Environ. Sci. 2015, 8, 855–861.
doi: 10.1039/C4EE03454F

(20) Morales-Guio, C. G.; Liardet, L.; Mayer, M. T.; Tilley, S. D.; Grätzel, M.; Hu, X. Photoelectrochemical Hydrogen Production in Alkaline Solutions Using Cu2O Coated with Earth-Abundant Hydrogen Evolution Catalysts. Angew. Chemie Int. Ed. 2015, 54, 664–667.
doi: 10.1002/anie.201410569

(19) Cendula, P.; Tilley, S. D.; Gimenez, S.; Bisquert, J.; Schmid, M.; Grätzel, M.; Schumacher, J. O. Calculation of the Energy Band Diagram of a Photoelectrochemical Water Splitting Cell. J. Phys. Chem. C 2014, 118, 29599–29607.
doi: 10.1021/jp509719d

(18) Luo, J.; Im, J.-H.; Mayer, M. T.; Schreier, M.; Nazeeruddin, M. K.; Park, N.-G.; Tilley, S. D.; Fan, H. J.; Gratzel, M. Water Photolysis at 12.3% efficiency via perovskite photovoltaics and Earth-abundant catalysis. Science 2014, 345, 1593.
doi: 10.1126/science.1258307

(17) Azevedo, J.; Steier, L.; Dias, P.; Stefik, M.; Sousa, C. T.; Araújo, J. P.; Mendes, A.; Graetzel, M.; Tilley, S. D.* On the Stability Enhancement of Cuprous Oxide Water Splitting Photocathodes by Low Temperature Steam Annealing. Energy Environ. Sci. 2014, 7, 4044–4052.
doi: 10.1039/C4EE02160F

(16) Steier, L.; Herraiz-Cardona, I.; Gimenez, S.; Fabregat-Santiago, F.; Bisquert, J.; Tilley, S. D.;* Grätzel, M. Understanding the Role of Underlayers and Overlayers in Thin Film Hematite Photoanodes. Adv. Funct. Mater. 2014, 24, 7681–7688.
doi: 10.1002/adfm.201402742

(15) Pendlebury, S. R.; Wang, X.; Formal, F. Le; Cornuz, M.; Kafizas, A.; Tilley, S. D.; Graetzel, M.; Durrant, J. R. Ultrafast Charge Carrier Recombination and Trapping in Hematite Photoanodes under Applied Bias. J. Am. Chem. Soc. 2014, 136, 9854.
doi: 10.1021/ja504473e

(14) Bornoz, P.; Abdi, F. F.; Tilley, S. D.; Dam, B.; van de Krol, R.; Grätzel, M.; Sivula, K. A Bismuth Vanadate–Cuprous Oxide Tandem Cell for Overall Solar Water Splitting. J. Phys. Chem. C 2014, 118, 16959.
doi: 10.1021/jp500441h

(13) Morales-Guio, C. G.; Tilley, S. D.; Vrubel, H.; Grätzel, M.; Hu, X. Hydrogen evolution from a copper(I) oxide photocathode coated with an amorphous molybdenum sulphide catalyst. Nat. Commun. 2014, 5, 3059.
doi: 10.1038/ncomms4059

(12) Tilley, S. David;* Schreier, M.; Azevedo, J.; Stefik, M.; Grätzel, M. Ruthenium Oxide Hydrogen Evolution Catalysis on Composite Cuprous Oxide Water Splitting PhotocathodesAdv. Func. Mat. 2014, 24, 303.
doi: 10.1002/adfm.201301106

(11) Le Formal, F.; Pendlebury, S. R.; Cornuz, M.; Tilley, S. David; Grätzel, M.; Durrant, J. R. Back electron-hole recombination in hematite photoanodes for water splitting. J. Am. Chem. Soc. 2014, 136, 2564.
doi: 10.1021/ja412058x

(10) Seger, B.; Tilley, S. David, Pedersen, T.; Vesborg, P.; Hansen, O.; Graetzel, M.; Chorkendorff, I. Silicon Protected with Atomic Layer Deposited TiO2: Conducting Versus Tunnelling Through TiO2. J. Mater. Chem. A. 2013, 1, 15089.
doi: 10.1039/c3ta12309j

(9) Seger, B.; Tilley, S. David, Pedersen, T.; Vesborg, P.; Hansen, O.; Graetzel, M.; Chorkendorff, I. Silicon Protected with Atomic Layer Deposited TiO2 – Durability Studies of Photocathodic H2 Evolution. RSC Adv. 2013, 3, 25902.
doi: 10.1039/c3ra45966g

(8) Reber, K.; Tilley, S. David; Carson, C.; Sorensen, E. Toward a synthesis of hirsutellone B by the concept of double cyclization. J. Org. Chem. 2013, 78, 9584-9607.
doi: 10.1021/jo401799f

(7) Rovelli, L.; Tilley, S. David; Sivula, K. Optimization and stabilization of electrodeposited p-type Cu2ZnSnS4 photocathodes for solar water reduction. ACS Appl. Mater. Interfaces 2013, 5, 8018-8024.
doi: 10.1021/am402096r

(6) Paracchino, A.; Matthews, N.; Hisatomi, T.; Stefik, M.; Tilley, S. David;* Grätzel, M. Ultrathin Films on Copper(I) Oxide Water Splitting Photocathodes: a Study on Performance and StabilityEnergy Environ. Sci. 2012, 5, 8673-8681.
doi: 10.1039/c2ee22063f

(5) Tilley, S. David; Cornuz, M.; Sivula, K., Grätzel, M. Light-Induced Water Splitting with Hematite: Improved Nanostructure and Iridium Oxide CatalysisAngew. Chem. Int. Ed. 2010, 49, 6405-6408. Featured in Nature, 2010, 466, 669.
doi: 10.1002/anie.201003110

(4) Reber, Keith P.; Tilley, S. David; Sorensen, Erik J. Bond formations by intermolecular and intramolecular trappings of acylketenes and their applications in natural product synthesis. Chem. Soc. Rev. 2009, 38, 3022-3034.
doi: 10.1039/b912599j

(3) Tilley, S. David; Reber, Keith P.; Sorensen, Erik J. A Rapid, Asymmetric Synthesis of the Decahydrofluorene Core of the Hirsutellones. Organic Letters. 2009, 11, 701-703.
doi: 10.1021/ol802768p

(2) Tilley, S. David; Joshi, N. S.; Francis, M. B. Proteins: Chemistry and Chemical Reactivity. In Wiley Encyclopedia of Chemical Biology; Tadhg P. Begley, Ed.; Wiley-VCH, 2009, 4, 158-174.
doi: 10.1002/9780470048672.wecb493

(1) Tilley, S. David; Francis, Matthew B. Tyrosine-Selective Protein Alkylation Using πAllylpalladium Complexes. J. Am. Chem. Soc. 2006, 128, 1080-1081.
doi: 10.1021/ja057106k